methyl formate Thermodynamic Properties vs Temperature (CAS 107-31-3)

Analyze how thermophysical properties change over a temperature range at a constant pressure of 1 atm.

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Property Profile for methyl formate

Calculated properties vs. Temperature

Profile Data

Equilibrium Thermodynamic and Transport Properties of methyl formate at 1.01325 bar over -23.15–226.85 °C
Temperature (°C)Specific heat capacity (kJ/kg·K)Density (kg/m³)Dynamic viscosity (cP)Thermal conductivity (W/m·K)Prandtl number ()Molar volume (m³/kmol)Specific enthalpy (kJ)Specific entropy (kJ/kg·K)Phase
-23.151.341591034.30.6109490.2005144.08770.0580607-69.565-0.253951l
-18.0481.364231027.460.5628260.1984883.868370.058447-62.6623-0.226619l
-12.94591.386581020.560.5210410.1964623.677380.0588421-55.6448-0.199382l
-7.843881.408641013.60.4845730.1944363.51060.0592464-48.514-0.172244l
-2.741841.430391006.560.4525960.192413.364650.0596603-41.2714-0.145205l
2.36021.45186999.460.4244310.1903843.23670.0600844-33.9186-0.118267l
7.462241.47303992.2810.3995230.1883573.124420.0605191-26.4571-0.0914327l
12.56431.4939985.0230.3774090.1863313.025860.060965-18.8882-0.064703l
17.66631.51448977.6850.3577060.1843052.939360.0614226-11.2137-0.0380796l
22.76841.53477970.260.3400910.1822792.863520.0618926-3.43484-0.0115638l
27.87041.55476962.7460.3242930.1802522.797170.06237574.446720.0148429l
32.97241.129372.390640.009687580.01371060.79798925.1196481.0981.57902g
38.07451.142182.351450.009862990.01413380.79704925.5383486.9591.59801g
43.17651.154962.313520.01003820.0145620.79615825.9569492.8831.61689g
48.27861.16772.27680.01021310.01499520.79530826.3756498.8691.63566g
53.38061.18042.241230.01038780.01543340.79449526.7942504.9181.65433g
58.48271.193062.206750.01056220.01587650.79371327.2129511.0291.6729g
63.58471.205682.173310.01073640.01632450.79295727.6316517.2031.69138g
68.68671.218262.140870.01091030.01677760.79222128.0502523.4391.70976g
73.78881.230792.109390.01108390.01723550.79150128.4689529.7381.72805g
78.89081.243282.078820.01125720.01769850.79079328.8875536.0991.74625g
83.99291.255712.049120.01143030.01816640.79009229.3062542.5211.76436g
89.09491.26812.020260.0116030.01863930.78939629.7249549.0061.78239g
94.19691.280431.99220.01177540.01911710.78869930.1435555.5521.80033g
99.2991.292711.964910.01194750.01959990.78830.5622562.1591.8182g
104.4011.304931.938360.01211930.02008760.78729630.9808568.8281.83598g
109.5031.317081.912510.01229080.02058020.78658431.3995575.5571.85368g
114.6051.329181.887350.0124620.02107770.78586231.8182582.3471.87131g
119.7071.341211.862840.01263280.02158010.78512832.2368589.1971.88886g
124.8091.353171.838950.01280330.02208740.78438132.6555596.1081.90634g
129.9111.365051.815680.01297340.02259950.7836233.0741603.0781.92374g
135.0131.376871.792980.01314320.02311640.78284333.4928610.1081.94107g
140.1151.388611.770850.01331270.02363810.7820533.9115617.1971.95833g
145.2171.400281.749250.01348180.02416450.78123934.3301624.3441.97552g
150.3191.411871.728170.01365050.02469550.78041134.7488631.551.99264g
155.4211.423371.70760.01381890.02523130.77956535.1674638.8142.00969g
160.5231.43481.687510.01398690.02577160.77870135.5861646.1362.02668g
165.6261.446141.667890.01415460.02631650.77781936.0048653.5152.04359g
170.7281.457391.648720.01432190.02686590.77691936.4234660.9512.06044g
175.831.468561.629980.01448880.02741970.77600136.8421668.4432.07722g
180.9321.479641.611670.01465540.02797790.77506537.2607675.9912.09394g
186.0341.490631.593760.01482160.02854040.77411337.6794683.5952.11059g
191.1361.501541.576250.01498740.02910720.77314438.0981691.2542.12718g
196.2381.512351.559110.01515280.02967820.77215838.5167698.9682.1437g
201.341.523061.542350.01531790.03025330.77115838.9354706.7362.16016g
206.4421.533691.525940.01548250.03083250.77014239.354714.5582.17656g
211.5441.544221.509880.01564680.03141560.76911239.7727722.4332.1929g
216.6461.554661.494150.01581070.03200270.76806940.1914730.3622.20917g
221.7481.5651.478750.01597430.03259370.76701340.61738.3432.22538g
226.851.575251.463660.01613740.03318840.76594541.0287746.3752.24152g

Property Profiles for methyl formate

Heat Capacity (Cp) vs Temperature

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Density vs Temperature

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Thermal Conductivity vs Temperature

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Viscosity vs Temperature

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Thermodynamic Property Profile at Constant Pressure

This page presents the temperature-dependent thermodynamic and transport properties of methyl formate (CAS 107-31-3) calculated at a constant pressure of 1 atm (101325 Pa) over the temperature range 250-500 K.

The properties shown - specific heat capacity (Cp), density (ρ), dynamic viscosity (μ), thermal conductivity (k), Prandtl number (Pr), molar volume (Vm), specific enthalpy (H), and specific entropy (S) - are among the most commonly used parameters in chemical engineering calculations, process simulation, and thermal system design.

All values are generated programmatically using validated thermodynamic correlations and equations of state and represent equilibrium properties at the specified pressure.


Understanding the Property Trends

  • Specific heat capacity (Cp) indicates the amount of energy required to raise the temperature of methyl formate and is critical for energy balance and heat-exchanger design.
  • Density (ρ) and molar volume (Vm) describe volumetric behavior and are required for flow calculations, equipment sizing, and storage design.
  • Dynamic viscosity (μ) governs fluid flow resistance, influencing Reynolds number and pressure drop.
  • Thermal conductivity (k) and Prandtl number (Pr) are essential inputs for convective heat-transfer correlations.
  • Specific enthalpy (H) and specific entropy (S) are fundamental thermodynamic properties used in process modeling, compression, and expansion analysis.

Property trends with temperature may vary depending on molecular structure, intermolecular interactions, and phase stability.


Engineering Applications

The temperature-dependent properties of methyl formate at atmospheric pressure are commonly required in:

  • Heat exchanger and reactor design
  • Process simulation and thermodynamic modeling
  • Fluid flow and pressure-drop calculations
  • Energy balance and equipment sizing
  • Chemical engineering education and research

These profiles are particularly useful when evaluating system performance over a wide operating temperature range under near-ambient pressure conditions.


Frequently Asked Questions

At what pressure are these properties calculated?
All properties on this page are calculated at a constant pressure of 1 atm (101325 Pa).

Can these values be used in process simulation software?
Yes. The data is suitable for preliminary design, validation, and educational use. For licensed simulators, vendor-specific property packages should be referenced.

Can I change the pressure or temperature range?
Yes. Use the interactive controls above to generate custom property profiles at different pressures or temperature ranges.


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