tert-butyl hydroperoxide Thermodynamic Properties vs Temperature (CAS 75-91-2)

Analyze how thermophysical properties change over a temperature range at a constant pressure of 1 atm.

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Property Profile for tert-butyl hydroperoxide

Calculated properties vs. Temperature

Profile Data

Equilibrium Thermodynamic and Transport Properties of tert-butyl hydroperoxide at 1.01325 bar over -23.15–226.85 °C
Temperature (°C)Specific heat capacity (kJ/kg·K)Density (kg/m³)Dynamic viscosity (cP)Thermal conductivity (W/m·K)Prandtl number ()Molar volume (m³/kmol)Specific enthalpy (kJ)Specific entropy (kJ/kg·K)Phase
-23.151.262671078.99N/A N/A N/A 0.0835233-122.398-0.44916s
-18.0481.284431076.08N/A N/A N/A 0.0837492-115.9-0.423431s
-12.94591.30621073.17N/A N/A N/A 0.0839764-109.292-0.397782s
-7.843881.327991070.26N/A N/A N/A 0.0842048-102.572-0.372207s
-2.741841.75966952.1740.6203160.1478017.385270.0946476-50.47-0.177584l
2.36021.78188947.9270.6042870.1468017.334860.0950716-41.4354-0.144485l
7.462241.80388943.5980.5884680.1458027.280580.0955078-32.288-0.111587l
12.56431.82565939.1850.5728570.1448037.22250.0959566-23.0289-0.0788883l
17.66631.8472934.6860.5574570.1438037.160720.0964184-13.6592-0.0463846l
22.76841.86853930.10.5422650.1428047.095320.0968939-4.18022-0.0140732l
27.87041.88964925.4250.5272830.1418057.02640.09738345.407060.0180485l
32.97241.91053920.6580.512510.1408056.954040.097887515.10150.0499833l
38.07451.9312915.80.4979460.1398066.878340.098406924.90190.0817337l
43.17651.95164910.8470.4835910.1388076.799370.09894234.80720.113302l
48.27861.97186905.7980.4694450.1378076.717230.099493544.81620.144691l
53.38061.99186900.650.4555070.1368086.6320.10006254.92790.175902l
58.48272.01164895.4020.4417780.1358086.543780.10064965.1410.206937l
63.58472.0312890.050.4282570.1348096.452650.10125475.45450.237799l
68.68672.05054884.5940.4149430.133816.35870.10187885.86720.268489l
73.78882.06965879.030.4018360.132816.262020.10252396.3780.29901l
78.89082.08854873.3550.3889350.1318116.162690.103189106.9860.329362l
83.99292.10721867.5680.376240.1308116.060790.103878117.6890.359548l
89.09492.12566861.6630.363750.1298125.95640.10459128.4880.389569l
94.19692.14389855.6390.3514640.1288125.84960.105326139.3790.419426l
99.2992.1619849.4920.339380.1278135.740460.106088150.3640.449122l
104.4012.17968843.2170.3274970.1268135.629050.106878161.4390.478657l
109.5032.19724836.8120.3158120.1258145.515430.107696172.6050.508032l
114.6052.21458830.270.3043220.1248145.399590.108544183.860.53725l
119.7071.710752.795590.00987480.01866490.90508232.2368632.2221.64429g
124.8091.726872.759750.01001250.01917660.90163332.6555641.0621.66665g
129.9111.742872.724820.01014890.01969510.89809633.0741649.9831.68892g
135.0131.758752.690760.01028390.02022050.89448133.4928658.9821.71111g
140.1151.774512.657540.01041770.02075270.89079233.9115668.061.73321g
145.2171.790152.625130.01055030.02129180.88703834.3301677.2161.75523g
150.3191.805672.59350.01068180.02183790.88322434.7488686.4491.77717g
155.4211.821082.562630.01081210.0223910.87935435.1674695.761.79903g
160.5231.836362.532480.01094130.02295110.87543635.5861705.1471.8208g
165.6261.851532.503030.01106950.02351820.87147336.0048714.6111.84249g
170.7281.866592.474260.01119660.02409250.86746936.4234724.151.86411g
175.831.881522.446140.01132280.02467390.86342936.8421733.7641.88564g
180.9321.896342.418660.01144810.02526250.85935737.2607743.4521.9071g
186.0341.911052.391780.01157240.02585830.85525737.6794753.2141.92848g
191.1361.925642.36550.01169590.02646130.85113238.0981763.051.94978g
196.2381.940122.339790.01181840.02707160.84698638.5167772.9581.971g
201.341.954492.314630.01194020.02768920.84282138.9354782.9391.99215g
206.4421.968742.290010.01206120.02831410.8386439.354792.9922.01323g
211.5441.982882.26590.01218130.02894630.83444839.7727803.1162.03422g
216.6461.996912.24230.01230080.02958590.83024540.1914813.3112.05515g
221.7482.010832.219180.01241950.03023290.82603540.61823.5762.076g
226.852.024642.196540.01253750.03088730.8218241.0287833.912.09677g

Property Profiles for tert-butyl hydroperoxide

Heat Capacity (Cp) vs Temperature

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Density vs Temperature

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Thermal Conductivity vs Temperature

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Viscosity vs Temperature

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Thermodynamic Property Profile at Constant Pressure

This page presents the temperature-dependent thermodynamic and transport properties of tert-butyl hydroperoxide (CAS 75-91-2) calculated at a constant pressure of 1 atm (101325 Pa) over the temperature range 250-500 K.

The properties shown - specific heat capacity (Cp), density (ρ), dynamic viscosity (μ), thermal conductivity (k), Prandtl number (Pr), molar volume (Vm), specific enthalpy (H), and specific entropy (S) - are among the most commonly used parameters in chemical engineering calculations, process simulation, and thermal system design.

All values are generated programmatically using validated thermodynamic correlations and equations of state and represent equilibrium properties at the specified pressure.


Understanding the Property Trends

  • Specific heat capacity (Cp) indicates the amount of energy required to raise the temperature of tert-butyl hydroperoxide and is critical for energy balance and heat-exchanger design.
  • Density (ρ) and molar volume (Vm) describe volumetric behavior and are required for flow calculations, equipment sizing, and storage design.
  • Dynamic viscosity (μ) governs fluid flow resistance, influencing Reynolds number and pressure drop.
  • Thermal conductivity (k) and Prandtl number (Pr) are essential inputs for convective heat-transfer correlations.
  • Specific enthalpy (H) and specific entropy (S) are fundamental thermodynamic properties used in process modeling, compression, and expansion analysis.

Property trends with temperature may vary depending on molecular structure, intermolecular interactions, and phase stability.


Engineering Applications

The temperature-dependent properties of tert-butyl hydroperoxide at atmospheric pressure are commonly required in:

  • Heat exchanger and reactor design
  • Process simulation and thermodynamic modeling
  • Fluid flow and pressure-drop calculations
  • Energy balance and equipment sizing
  • Chemical engineering education and research

These profiles are particularly useful when evaluating system performance over a wide operating temperature range under near-ambient pressure conditions.


Frequently Asked Questions

At what pressure are these properties calculated?
All properties on this page are calculated at a constant pressure of 1 atm (101325 Pa).

Can these values be used in process simulation software?
Yes. The data is suitable for preliminary design, validation, and educational use. For licensed simulators, vendor-specific property packages should be referenced.

Can I change the pressure or temperature range?
Yes. Use the interactive controls above to generate custom property profiles at different pressures or temperature ranges.


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