citric acid Thermodynamic Properties vs Temperature (CAS 77-92-9)

Analyze how thermophysical properties change over a temperature range at a constant pressure of 1 atm.

Input Conditions

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Property Profile for citric acid

Calculated properties vs. Temperature

Profile Data

Equilibrium Thermodynamic and Transport Properties of citric acid at 1.01325 bar over -23.15–226.85 °C
Temperature (°C)Specific heat capacity (kJ/kg·K)Density (kg/m³)Dynamic viscosity (cP)Thermal conductivity (W/m·K)Prandtl number ()Molar volume (m³/kmol)Specific enthalpy (kJ)Specific entropy (kJ/kg·K)Phase
-23.150.8362291734.78N/A N/A N/A 0.110748-44.0846-0.160852s
-18.0480.8528861731.98N/A N/A N/A 0.110927-39.7757-0.14379s
-12.94590.8696021729.17N/A N/A N/A 0.111107-35.3816-0.126736s
-7.843880.8863761726.37N/A N/A N/A 0.111287-30.9021-0.109688s
-2.741840.903211723.57N/A N/A N/A 0.111468-26.3369-0.0926444s
2.36020.9201041720.77N/A N/A N/A 0.11165-21.6856-0.0756042s
7.462240.9370581717.97N/A N/A N/A 0.111832-16.9479-0.0585661s
12.56430.9540721715.17N/A N/A N/A 0.112015-12.1237-0.041529s
17.66630.9711481712.36N/A N/A N/A 0.112198-7.2124-0.0244917s
22.76840.9882851709.56N/A N/A N/A 0.112382-2.21387-0.00745326s
27.87041.005481706.76N/A N/A N/A 0.1125662.872250.00958741s
32.97241.022741703.96N/A N/A N/A 0.1127518.046270.0266312s
38.07451.040071701.16N/A N/A N/A 0.11293713.30850.0436792s
43.17651.057451698.36N/A N/A N/A 0.11312318.65930.0607321s
48.27861.07491695.55N/A N/A N/A 0.1133124.09890.0777908s
53.38061.092411692.75N/A N/A N/A 0.11349829.62780.0948561s
58.48271.109981689.95N/A N/A N/A 0.11368635.24610.111929s
63.58471.127621687.15N/A N/A N/A 0.11387540.95420.12901s
68.68671.145321684.35N/A N/A N/A 0.11406446.75250.146099s
73.78881.163081681.55N/A N/A N/A 0.11425452.64130.163199s
78.89081.180911678.74N/A N/A N/A 0.11444558.62080.180308s
83.99291.19881675.94N/A N/A N/A 0.11463664.69150.197428s
89.09491.216751673.14N/A N/A N/A 0.11482870.85360.21456s
94.19691.234771670.34N/A N/A N/A 0.11502177.10740.231703s
99.2991.252851667.54N/A N/A N/A 0.11521483.45340.248859s
104.4011.2711664.74N/A N/A N/A 0.11540889.89180.266028s
109.5031.289211661.93N/A N/A N/A 0.11560296.42290.28321s
114.6051.307481659.13N/A N/A N/A 0.115798103.0470.300407s
119.7071.325821656.33N/A N/A N/A 0.115993109.7650.317618s
124.8091.344231653.53N/A N/A N/A 0.11619116.5760.334844s
129.9111.362691650.73N/A N/A N/A 0.116387123.4810.352086s
135.0131.381231647.93N/A N/A N/A 0.116585130.4810.369343s
140.1151.399821645.12N/A N/A N/A 0.116784137.5760.386616s
145.2171.418481642.32N/A N/A N/A 0.116983144.7650.403907s
150.3191.437211639.52N/A N/A N/A 0.117183152.050.421214s
155.4211.695081460.921.409580.14661316.2970.131508359.8810.908908l
160.5231.705551457.461.381520.14561316.18160.131821368.5560.929031l
165.6261.715711453.921.353740.14461316.0610.132141377.2840.949038l
170.7281.725581450.321.326230.14361415.93530.13247386.0620.968931l
175.831.735161446.641.2990.14261415.80470.132807394.8910.988707l
180.9321.744431442.891.272040.14161515.66920.133152403.7681.00837l
186.0341.75341439.061.245360.14061515.5290.133506412.6911.02791l
191.1361.762081435.161.218950.13961515.38430.133869421.6591.04733l
196.2381.770451431.181.192810.13861615.23510.134241430.6711.06663l
201.341.778531427.121.166950.13761615.08150.134623439.7241.08582l
206.4421.786311422.981.141370.13661614.92380.135015448.8181.10488l
211.5441.793791418.751.116060.13561714.76190.135417457.9511.12382l
216.6461.800971414.441.091020.13461714.59610.13583467.1221.14265l
221.7481.807851410.041.066260.13361714.42650.136254476.3281.16134l
226.851.814431405.561.041770.13261814.25310.136689485.5691.17992l

Property Profiles for citric acid

Heat Capacity (Cp) vs Temperature

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Density vs Temperature

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Thermodynamic Property Profile at Constant Pressure

This page presents the temperature-dependent thermodynamic and transport properties of citric acid (CAS 77-92-9) calculated at a constant pressure of 1 atm (101325 Pa) over the temperature range 250-500 K.

The properties shown - specific heat capacity (Cp), density (ρ), dynamic viscosity (μ), thermal conductivity (k), Prandtl number (Pr), molar volume (Vm), specific enthalpy (H), and specific entropy (S) - are among the most commonly used parameters in chemical engineering calculations, process simulation, and thermal system design.

All values are generated programmatically using validated thermodynamic correlations and equations of state and represent equilibrium properties at the specified pressure.


Understanding the Property Trends

  • Specific heat capacity (Cp) indicates the amount of energy required to raise the temperature of citric acid and is critical for energy balance and heat-exchanger design.
  • Density (ρ) and molar volume (Vm) describe volumetric behavior and are required for flow calculations, equipment sizing, and storage design.
  • Dynamic viscosity (μ) governs fluid flow resistance, influencing Reynolds number and pressure drop.
  • Thermal conductivity (k) and Prandtl number (Pr) are essential inputs for convective heat-transfer correlations.
  • Specific enthalpy (H) and specific entropy (S) are fundamental thermodynamic properties used in process modeling, compression, and expansion analysis.

Property trends with temperature may vary depending on molecular structure, intermolecular interactions, and phase stability.


Engineering Applications

The temperature-dependent properties of citric acid at atmospheric pressure are commonly required in:

  • Heat exchanger and reactor design
  • Process simulation and thermodynamic modeling
  • Fluid flow and pressure-drop calculations
  • Energy balance and equipment sizing
  • Chemical engineering education and research

These profiles are particularly useful when evaluating system performance over a wide operating temperature range under near-ambient pressure conditions.


Frequently Asked Questions

At what pressure are these properties calculated?
All properties on this page are calculated at a constant pressure of 1 atm (101325 Pa).

Can these values be used in process simulation software?
Yes. The data is suitable for preliminary design, validation, and educational use. For licensed simulators, vendor-specific property packages should be referenced.

Can I change the pressure or temperature range?
Yes. Use the interactive controls above to generate custom property profiles at different pressures or temperature ranges.


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