phosphine (PH3) Thermodynamic Properties vs Temperature (CAS 7803-51-2)

Analyze how thermophysical properties change over a temperature range at a constant pressure of 1 atm.

Input Conditions

Define the chemical and range for the property profile.

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Property Profile for phosphine (PH3)

Calculated properties vs. Temperature

Profile Data

Equilibrium Thermodynamic and Transport Properties of phosphine (PH3) at 1.01325 bar over -23.15–226.85 °C
Temperature (°C)Specific heat capacity (kJ/kg·K)Density (kg/m³)Dynamic viscosity (cP)Thermal conductivity (W/m·K)Prandtl number ()Molar volume (m³/kmol)Specific enthalpy (kJ)Specific entropy (kJ/kg·K)Phase
-23.151.032751.657260.01058330.01525770.71634920.5143-51.5383-0.188387g
-18.0481.038971.624110.01079990.01563490.71767520.933-46.2032-0.167262g
-12.94591.045191.592270.01101360.01601460.71879921.3517-40.8386-0.14644g
-7.843881.051411.561650.01122460.01639710.71973721.7703-35.4443-0.12591g
-2.741841.057631.532180.01143290.01678240.72050322.189-30.0201-0.105659g
2.36021.063851.503810.01163880.01717060.72111222.6076-24.566-0.0856772g
7.462241.070071.476470.01184240.01756180.72157523.0263-19.0818-0.0659539g
12.56431.076291.45010.01204370.01795610.72190523.445-13.5675-0.0464796g
17.66631.082511.424660.0122430.01835340.72211323.8636-8.0229-0.027245g
22.76841.088731.40010.01244030.01875390.72220924.2823-2.44801-0.00824153g
27.87041.094971.376370.01263580.01915780.72220424.70093.15730.010539g
32.97241.101321.353430.01282940.01956650.72211525.11968.793430.0291053g
38.07451.107761.331240.01302140.01998010.72194925.538314.4610.0474666g
43.17651.11431.309770.01321170.02039830.72171525.956920.16050.0656312g
48.27861.120911.288980.01340060.02082130.72141826.375625.89250.083607g
53.38061.127611.268840.01358790.02124880.72106626.794231.65750.101401g
58.48271.134371.249320.01377380.02168090.72066327.212937.45570.119021g
63.58471.141191.230390.01395850.02211730.72021527.631643.28770.136473g
68.68671.148061.212030.01414180.02255810.71972828.050249.15380.153763g
73.78881.154981.19420.01432390.0230030.71920728.468955.05420.170896g
78.89081.161951.176890.01450490.0234520.71865628.887560.98930.187878g
83.99291.168951.160080.01468470.02390510.71807929.306266.95920.204714g
89.09491.175991.143740.01486350.0243620.71748129.724972.96410.221409g
94.19691.183051.127860.01504130.02482280.71686530.143579.00440.237967g
99.2991.190141.112410.01521810.02528720.71623630.562285.08010.254392g
104.4011.197251.097370.01539390.02575510.71559530.980891.19130.270689g
109.5031.204371.082740.01556880.02622660.71494731.399597.33830.286861g
114.6051.211511.06850.01574290.02670140.71429431.8182103.5210.302912g
119.7071.218661.054620.01591610.02717950.71363932.2368109.740.318845g
124.8091.225821.04110.01608850.02766070.71298332.6555115.9940.334663g
129.9111.232981.027920.01626020.02814490.7123333.0741122.2850.35037g
135.0131.240151.015070.01643110.02863210.71168233.4928128.6120.365968g
140.1151.247311.002540.01660130.02912210.71103933.9115134.9740.38146g
145.2171.254480.9903130.01677080.02961490.71040434.3301141.3730.396848g
150.3191.261640.9783820.01693960.03011030.70977934.7488147.8080.412136g
155.4211.268790.9667350.01710780.03060820.70916535.1674154.2790.427326g
160.5231.275940.9553610.01727540.03110850.70856235.5861160.7860.44242g
165.6261.283070.9442520.01744240.03161120.70797336.0048167.3290.457419g
170.7281.29020.9333990.01760880.03211610.70739836.4234173.9090.472327g
175.831.297310.9227920.01777460.03262310.70683936.8421180.5240.487145g
180.9321.304410.9124240.01793990.03313220.70629537.2607187.1750.501875g
186.0341.31150.9022860.01810470.03364330.70576837.6794193.8620.516519g
191.1361.318570.892370.0182690.03415620.70525938.0981200.5840.531079g
196.2381.325620.8826710.01843280.03467090.70476738.5167207.3430.545556g
201.341.332650.873180.01859620.03518730.70429438.9354214.1370.559951g
206.4421.339660.863890.0187590.03570530.70383939.354220.9660.574268g
211.5441.346660.8547970.01892150.03622490.70340439.7727227.8310.588506g
216.6461.353630.8458930.01908350.03674590.70298840.1914234.7310.602668g
221.7481.360580.8371720.01924510.03726830.70259240.61241.6670.616755g
226.851.36750.828630.01940630.03779190.70221641.0287248.6380.630768g

Property Profiles for phosphine (PH3)

Heat Capacity (Cp) vs Temperature

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Density vs Temperature

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Thermal Conductivity vs Temperature

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Viscosity vs Temperature

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Thermodynamic Property Profile at Constant Pressure

This page presents the temperature-dependent thermodynamic and transport properties of phosphine (PH3) (CAS 7803-51-2) calculated at a constant pressure of 1 atm (101325 Pa) over the temperature range 250-500 K.

The properties shown - specific heat capacity (Cp), density (ρ), dynamic viscosity (μ), thermal conductivity (k), Prandtl number (Pr), molar volume (Vm), specific enthalpy (H), and specific entropy (S) - are among the most commonly used parameters in chemical engineering calculations, process simulation, and thermal system design.

All values are generated programmatically using validated thermodynamic correlations and equations of state and represent equilibrium properties at the specified pressure.


Understanding the Property Trends

  • Specific heat capacity (Cp) indicates the amount of energy required to raise the temperature of phosphine (PH3) and is critical for energy balance and heat-exchanger design.
  • Density (ρ) and molar volume (Vm) describe volumetric behavior and are required for flow calculations, equipment sizing, and storage design.
  • Dynamic viscosity (μ) governs fluid flow resistance, influencing Reynolds number and pressure drop.
  • Thermal conductivity (k) and Prandtl number (Pr) are essential inputs for convective heat-transfer correlations.
  • Specific enthalpy (H) and specific entropy (S) are fundamental thermodynamic properties used in process modeling, compression, and expansion analysis.

Property trends with temperature may vary depending on molecular structure, intermolecular interactions, and phase stability.


Engineering Applications

The temperature-dependent properties of phosphine (PH3) at atmospheric pressure are commonly required in:

  • Heat exchanger and reactor design
  • Process simulation and thermodynamic modeling
  • Fluid flow and pressure-drop calculations
  • Energy balance and equipment sizing
  • Chemical engineering education and research

These profiles are particularly useful when evaluating system performance over a wide operating temperature range under near-ambient pressure conditions.


Frequently Asked Questions

At what pressure are these properties calculated?
All properties on this page are calculated at a constant pressure of 1 atm (101325 Pa).

Can these values be used in process simulation software?
Yes. The data is suitable for preliminary design, validation, and educational use. For licensed simulators, vendor-specific property packages should be referenced.

Can I change the pressure or temperature range?
Yes. Use the interactive controls above to generate custom property profiles at different pressures or temperature ranges.


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